Dichlorido{1-[N-(5-chloro-2-oxidophenyl)carboximidoyl]naphthalen-2-olato-κ3 O,N,O′}(methanol-κO)tin(IV)
نویسندگان
چکیده
In the title complex, [Sn(C(17)H(10)ClNO(2))Cl(2)(CH(3)OH)], the Sn(IV) atom features a distorted octa-hedral geometry defined by the O,N,O'-donors of the dianion, two Cl atoms and the methanol O atom. The six-membered chelate ring has a half-chair conformation with the Sn atom lying 0.449 (4) Å out of the plane defined by the remaining atoms (r.m.s. deviation = 0.0238 Å). Supra-molecular helical chains along [100], mediated by O-H⋯O hydrogen bonds, feature in the crystal packing. Chains are linked by C-H⋯O, C-H⋯Cl and π-π [centroid-centroid distance = 3.598 (2) Å] inter-actions.
منابع مشابه
{4-Bromo-2-[(5-chloro-2-oxidophenyl)iminomethyl]phenolato-κ3 O,N,O′}(methanol-κO)(methanolato-κO)oxidovanadium(V)
The title Schiff base complex, [V(C(13)H(7)BrClNO(2))(CH(3)O)O(CH(3)OH)], features a vanadyl group, a tridentate Schiff base ligand, and coordinated methanol and methano-late ligands. The NO(5) donor set is based on a distorted octa-hedron. Helical supra-molecular chains along [010] are found in the crystal structure mediated by O-H⋯O hydrogen bonds formed between the coordinating methanol mol-...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012